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Active Site Identification and Evaluation Criteria of In Situ Grown CoTe and NiTe Nanoarrays for Hydrogen Evolution and Oxygen Evolution Reactions
Author(s) -
Yang Liu,
Xu Haoxiang,
Liu Huibing,
Cheng Daojian,
Cao Dapeng
Publication year - 2019
Publication title -
small methods
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 4.66
H-Index - 46
ISSN - 2366-9608
DOI - 10.1002/smtd.201900113
Subject(s) - overpotential , oxygen evolution , water splitting , catalysis , desorption , dissociation (chemistry) , bifunctional , adsorption , materials science , hydrothermal circulation , chemical engineering , yield (engineering) , in situ , nanotechnology , chemistry , electrode , electrochemistry , metallurgy , organic chemistry , photocatalysis , engineering
Abstract Developing efficient non‐precious bifunctional electrocatalysts for oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) is highly critical for overall water splitting. Herein, vertically aligned CoTe and NiTe nanoarrays are synthesized in situ grown on Ni foams (marked as CoTeNR/NF and NiTeNR/NF) via a facile hydrothermal method, and further explore their catalytic activities for overall water splitting. The CoTeNR/NF catalyst exhibits not only excellent OER performance with a low overpotential of 350 mV to deliver 100 mA cm −2 , but also high HER activity only requiring 202 mV overpotential to yield 10 mA cm −2 in alkaline condition. Moreover, experimental technique and density functional theory are combined together to reveal that the real active sites of CoTeNR/NF for OER are from the in situ generated CoOOHspecies on CoTeNR/NF in the OER process, and also propose a new HER performance evaluation criteria of using H 2 O adsorption energy, H 2 O dissociation barrier, and H 2 /OH − desorption energy as an indicator. The new criteria can satisfactorily evaluate the HER performance of as‐synthesized samples, while the traditional one of using H adsorption energy as an indicator fails in the HER performance evaluation of as‐synthesized samples. It is expected that the new evaluation criteria can be used as a general criteria to evaluate the HER performance of other electrocatalysts.