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Recent Progress on Electrocatalyst and Photocatalyst Design for Nitrogen Reduction
Author(s) -
Li Mengqiao,
Huang Hao,
Low Jingxiang,
Gao Chao,
Long Ran,
Xiong Yujie
Publication year - 2019
Publication title -
small methods
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 4.66
H-Index - 46
ISSN - 2366-9608
DOI - 10.1002/smtd.201800388
Subject(s) - photocatalysis , electrocatalyst , ammonia production , ammonia , nitrogen fixation , nanotechnology , biochemical engineering , production (economics) , environmental science , materials science , catalysis , process engineering , nitrogen , chemistry , engineering , electrochemistry , biochemistry , organic chemistry , electrode , economics , macroeconomics
Ammonia is one of the most important chemicals due to its enormous applications in fertilizer production and as an energy carrier. The production of ammonia mainly relies on the traditional Haber–Bosch process under high temperature and pressure, leading to massive energy consumption and notable environmental issues. Recently, electrocatalytic and photocatalytic nitrogen (N 2 ) fixation have emerged for achieving green production of ammonia owing to their features of environmental friendliness and cost‐effectiveness. However, ammonia production through electrocatalysis and photocatalysis is still far away from practical applications. To facilitate the practical applications, a thorough understanding of nitrogen fixation is highly desired for the future design of high‐efficiency catalysts. Here, the fundamental investigations on electrocatalytic and photocatalytic N 2 reduction are summarized. Based on the fundamental understanding, the current approaches and design strategies for heterogeneous catalysts toward electrocatalytic and photocatalytic N 2 reduction are then presented. Finally, the remaining challenges and future opportunities in this field are outlined, leveraging the existing understanding on structure–property relationships. It is anticipated that this review sheds some light on the development of advanced catalytic systems for ammonia production through N 2 fixation.