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Revealing the Critical Role of Titanium in Layered Manganese‐Based Oxides toward Advanced Sodium‐Ion Batteries via a Combined Experimental and Theoretical Study
Author(s) -
Fang Tiancheng,
Guo Shaohua,
Jiang Kezhu,
Zhang Xiaoyu,
Wang Di,
Feng Yuzhang,
Zhang Xueping,
Wang Peng,
He Ping,
Zhou Haoshen
Publication year - 2019
Publication title -
small methods
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 4.66
H-Index - 46
ISSN - 2366-9608
DOI - 10.1002/smtd.201800183
Subject(s) - manganese , cathode , materials science , intercalation (chemistry) , dissolution , electrochemistry , sodium , titanium , chemical engineering , octahedron , ion , energy storage , inorganic chemistry , electrode , nanotechnology , chemistry , metallurgy , thermodynamics , organic chemistry , engineering , power (physics) , physics
Sodium‐ion batteries are one of the most promising candidates for large‐scale energy storage. Manganese‐based layered oxides are extensively studied as a cathode of sodium‐ion batteries due to the low cost and high electrochemical activity. However, these layered cathodes usually suffer from the severe manganese dissolution originated from Jahn–Teller distortion, thereby leading to severe capacity fading and structural deterioration. Herein, it is demonstrated via a combined experimental and theoretical study, titanium substitution in layered manganese‐based oxides can weaken the Jahn–Teller effect, minimize the relative dissolution, and thus enable robust sodium storage during long‐term operation. Results reveal that Ti‐doping can restrain shrinkage or elongation of the MnO octahedral structure to minimize the Jahn–Teller distortion for Mn atoms surrounded by titanium. Consequently, P2‐Na 0.86 Co 0.475 Mn 0.475 Ti 0.05 O 2 can deliver a reversible capacity over 110 mAh g −1 , good rate capability, and superior long‐cycling performance (81.1% cycle retention after 200 cycles at high rate of 5 C). The findings provide new opportunities for design of high‐performance electrodes for sodium‐ion batteries and deepen the understanding of intercalation chemistry in layered structures.