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General and Scalable Solid‐State Synthesis of 2D MPS 3 (M = Fe, Co, Ni) Nanosheets and Tuning Their Li/Na Storage Properties
Author(s) -
Liang Qinghua,
Zheng Yun,
Du Chengfeng,
Luo Yubo,
Zhang Jianli,
Li Bing,
Zong Yun,
Yan Qingyu
Publication year - 2017
Publication title -
small methods
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 4.66
H-Index - 46
ISSN - 2366-9608
DOI - 10.1002/smtd.201700304
Subject(s) - materials science , propylamine , nanomaterials , intercalation (chemistry) , nanotechnology , chemical engineering , energy storage , ternary operation , lamellar structure , diffusion , metal , ion , inorganic chemistry , chemistry , computer science , organic chemistry , physics , engineering , power (physics) , quantum mechanics , amine gas treating , metallurgy , composite material , thermodynamics , programming language
The scalable preparation of 2D nanomaterials is challenging and highly desirable for fundamental interest and practical applications. Herein, an efficient solid‐state method is developed for producing emerging 2D ternary layered metal phosphorus trichalcogenide (MPS 3 , M = Fe, Co, Ni) nanosheets on a large scale. The high‐quality MPS 3 single‐crystal nanosheets are exposed with (00l) facets and have an average lateral size of ≈200 nm and an average thickness of ≈18 nm. Moreover, their interlayer spacing can be expanded by intercalating propylamine at room temperature. For Li/Na storage applications, such MPS 3 nanosheets can achieve: i) high specific capacity owing to the intrinsic composition, realizing a theoretical specific capacity higher than the corresponding metal oxides, and ii) superior rate capability due to the large extrinsic pseudocapacitive contribution from surface redox reactions. Remarkably, the propylamine‐intercalated samples show improved Li/Na storage performance due to the better electrical conductivity and enlarged interlayer distance to allow easier ion accessibility and faster ion diffusion. Impressively, the Na‐ion batteries based on the intercalated NiPS 3 nanosheets deliver 1090 and 536 mA h g −1 at 0.05 and 5.0 A g −1 , respectively. This work paves the way for developing MPS 3 nanosheets for energy storage and conversion, catalysis, and so on.