Open AccessNoncovalent Immobilization of Pentamethylcyclopentadienyl Iridium Complexes on Ordered Mesoporous Carbon for Electrocatalytic Water Oxidation
Author(s) -
Geer Ana M.,
Liu Chang,
Musgrave Charles B.,
Webber Christopher,
Johnson Grayson,
Zhou Hua,
Sun Cheng-Jun,
Dickie Diane A.,
Goddard William A.,
Zhang Sen,
Gunnoe T. Brent
Publication year - 2021
Publication title -
small science
Language(s) - English
Resource type - Journals
ISSN - 2688-4046
DOI - 10.1002/smsc.202170027
Subject(s) - iridium , mesoporous material , electrochemistry , chemistry , catalysis , inorganic chemistry , stacking , oxidation state , electrocatalyst , electrode , organic chemistry
Molecular Iridium Complexes for Electrocatalytic Water Oxidation In article number 2100037 , Ana M. Geer, William A. Goddard III, Sen Zhang, T. Brent Gunnoe, and co‐workers report that iridium‐based solid‐state water oxidation anodes are prepared by immobilizing cyclopentadienyl iridium (III) complexes onto ordered mesoporous carbon via π‐stacking. The heterogenized molecular catalysts exhibit high turnover frequencies at low overpotentials for electrochemical water oxidation under the acidic conditions.