Open AccessOrganic Cation Engineering for Vertical Charge Transport in Lead‐Free Perovskite Quantum Wells
Author(s) -
Ma Ke,
Hsu Sheng-Ning,
Gao Yao,
Wei Zitang,
Jin Linrui,
Finkenauer Blake P.,
Huang Libai,
Boudouris Bryan W.,
Mei Jianguo,
Dou Letian
Publication year - 2021
Publication title -
small science
Language(s) - English
Resource type - Journals
ISSN - 2688-4046
DOI - 10.1002/smsc.202000024
Subject(s) - halide , iodide , perovskite (structure) , octahedron , materials science , charge carrier , photovoltaic system , chemistry , inorganic chemistry , chemical engineering , optoelectronics , crystallography , ion , organic chemistry , engineering , ecology , biology
2D organic–inorganic hybrid halide perovskites are promising semiconductor materials for a variety of device applications. However, fundamental issues of charge transport through multiple quantum wells separated by bulky organic ligands remain unsolved. Herein, a mixture of π‐conjugated organic ligands, (2‐(3‴,4′‐dimethyl‐[2,2′:5′,2′:5″,2‴‐quaterthiophen]‐5‐yl)ethan‐1‐ammonium iodide) (4Tm) and 2‐([2,2′‐bithiophen]‐5‐yl)ethan‐1‐aminium iodide (2T), is used as spacer to form (4Tm) x (2T) 2− x SnI 4 2D perovskite thin films. The new strategy of alloying 2T into 4Tm ligands reduces the interlayer distance (barrier thickness) while maintaining the relatively small energy barrier height for the hybrid quantum wells, enhances interlayer interactions, and improves charge transport across adjacent perovskite layers. Moreover, solar cell devices fabricated with (4Tm) x (2T) 2− x SnI 4 exhibit improved photovoltaic properties and stability.