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Covalent–Organic Frameworks: Single‐Pore versus Dual‐Pore Bipyridine‐Based Covalent–Organic Frameworks: An Insight into the Heterogeneous Catalytic Activity for Selective CH Functionalization (Small 22/2021)
Author(s) -
Vardhan Harsh,
AlEnizi Abdullah M.,
Nafady Ayman,
Pan Yanxiong,
Yang Zhongyu,
Gutiérrez Humberto R.,
Han Xiaolong,
Ma Shengqian
Publication year - 2021
Publication title -
small
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.785
H-Index - 236
eISSN - 1613-6829
pISSN - 1613-6810
DOI - 10.1002/smll.202170109
Subject(s) - surface modification , covalent organic framework , covalent bond , catalysis , reusability , materials science , metal organic framework , combinatorial chemistry , palladium , regioselectivity , bipyridine , chemistry , nanotechnology , chemical engineering , organic chemistry , computer science , adsorption , software , crystal structure , programming language , engineering
Transition metal catalyzed carbon—hydrogen functionalization imparts a paradigm shift in the complex target synthesis, including pharmaceutical and material science applications. To establish structure‐function‐property relationship of covalent organic frameworks, palladium docked dual‐pore COFs with controllable bipyridine content exhibit regioselective C—H to C—X (X = Cl, Br, I) and C—O functionalization, and compared with single pore framework. This protocol presented by Shengqian Ma and co‐workers (article number 2003970) features high efficiency, remarkable reusability, and recyclability.