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Halogen Bonding: Halogen‐Bond Mediated 3D Confined Assembly of AB Diblock Copolymer and C Homopolymer Blends (Small 18/2021)
Author(s) -
Zheng Xihuang,
Ren Min,
Wang Huayang,
Wang Huiying,
Geng Zhen,
Xu Jiangping,
Deng Renhua,
Chen Senbin,
Binder Wolfgang H.,
Zhu Jintao
Publication year - 2021
Publication title -
small
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.785
H-Index - 236
eISSN - 1613-6829
pISSN - 1613-6810
DOI - 10.1002/smll.202170082
Subject(s) - copolymer , materials science , lamellar structure , halogen , polymer chemistry , halogen bond , polymer , acceptor , chemical engineering , chemistry , organic chemistry , composite material , alkyl , physics , engineering , condensed matter physics
Halogen‐bond mediated 3D confined assembly gives rise to a profound picture of morphological transition when combining with polymer donor‐acceptor pairs, changing from spherical to cylindrical, lamellar, and then to inverse cylindrical structures, by tuning the feeding ratio and choice of surfactant (presented by Senbin Chen, Wolfgang H. Binder, Jintao Zhu, and co‐workers in article number 2007570). Subsequent selective swelling/deswelling triggers the formation of mesoporous microparticles, disassembled nanodiscs, and superaggregates.