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Solid Solution of Bi and Sb for Robust Lithium Storage Enabled by Consecutive Alloying Reaction
Author(s) -
Wang Yutao,
Yu Ruohan,
Luo Tingting,
Ma Ganggang,
Hu Guangwu,
Lyu Jiahui,
Zhou Liang,
Wu Jinsong
Publication year - 2021
Publication title -
small
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.785
H-Index - 236
eISSN - 1613-6829
pISSN - 1613-6810
DOI - 10.1002/smll.202102915
Subject(s) - materials science , alloy , lithium (medication) , electrolyte , chemical engineering , redox , carbon fibers , solid solution , ion , electrode , nanotechnology , metallurgy , composite material , chemistry , organic chemistry , composite number , medicine , engineering , endocrinology
Materials with alloying reactions have significant potential as electrodes for lithium‐ion batteries (LIBs) due to its high theoretical capacity and appropriate lithiation potentials. Nonetheless, their cycling performance is inferior due to violent volume expansion and severe pulverization of active materials. Herein, solid solution of Bi 0.5 Sb 0.5 encapsulated with carbon is discovered to enable consecutive alloying reactions with manageable volume change, suitable for developing LIBs with high capacity and robust cyclability. A Sb‐rich shell and Bi‐rich core structure is formed in cycling since the alloying reaction between Sb and Li occurs first, followed by the alloying reaction between Bi and Li. Such a consecutive alloying reaction obeying the thermodynamic path is experimentally realized by the carbon capsulation, which acts as a protecting solid layer to avoid polarized reactions occurred when exposed directly to liquid electrolyte. The LIBs using Bi 0.5 Sb 0.5 @carbon run on the consecutive alloying reactions exhibits high capacity, prolonged lifespan (489.4 mAh g −1 after 2000 cycles at 1 A g −1 ) and fast kinetic, while those using bare Bi 0.5 Sb 0.5 suffer from worsened kinetic and thus a poor cycling performance owning to the polarized reactions. The work paves a way of developing alloy electrodes for alkaline‐ion rechargeable batteries with potential industry applications.