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Single Zinc Atoms Anchored on MOF‐Derived N‐Doped Carbon Shell Cooperated with Magnetic Core as an Ultrawideband Microwave Absorber
Author(s) -
Huang Mengqiu,
Wang Lei,
You Wenbin,
Che Renchao
Publication year - 2021
Publication title -
small
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.785
H-Index - 236
eISSN - 1613-6829
pISSN - 1613-6810
DOI - 10.1002/smll.202101416
Subject(s) - materials science , reflection loss , carbon fibers , dielectric , doping , dielectric loss , microwave , polarization (electrochemistry) , absorption (acoustics) , nanotechnology , composite material , optoelectronics , composite number , chemistry , physics , quantum mechanics
Polarization behaviors of no‐magnetic shell dominate the dielectric properties for core–shell magnetic‐carbon composites, which faces a huge challenge. Herein, a single atom‐doping strategy is established to adjust local electric potential in the metal‐organic framework (MOF)‐derived carbon shell. Benefiting from the confined transformation, single Zn atoms and N atoms are evenly distributed in the porous carbon shell using ZIF‐8 as a template. Dielectric assembled carbon layers with functionalized Fe 3 O 4 core construct unique magnetic‐dielectric synergy system. The electromagnetic parameters of Fe 3 O 4 @Zn‐N‐Carbon composites can be modified by tuning the pod‐like Zn‐N‐doping carbon shell via repeating ZIF‐8 growth cycles. Surprisingly, the core–shell Fe 3 O 4 @Zn‐N‐Carbon exhibits superior microwave absorption (MA) performance both in the reflection loss ability and wide‐frequency responding feature. The reflection loss value of Fe 3 O 4 @Zn‐N‐Carbon microspheres reach −61.9 dB and the effective absorption bandwidth up to 11.5 GHz at only 2.5 mm thickness. The excellent MA mechanism is ascribed to following reasons. High‐density stacking Zn‐N doping carbon layers boost the interfacial polarization and plentiful Zn single atoms maximize the dipole polarization because of maximum atom utilization efficiency. Enhanced magnetic loss ability results from the compulsory magnetic coupling responding among Fe 3 O 4 cores. Magnetic‐dielectric synergy of core–shell Fe 3 O 4 @Zn‐N‐Carbon microspheres can build ultrawide MA frequency.