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Fabrication of an Au 25 ‐Cys‐Mo Electrocatalyst for Efficient Nitrogen Reduction to Ammonia under Ambient Conditions
Author(s) -
Tan Yuan,
Yan Lei,
Huang Chuanqi,
Zhang Wenna,
Qi Haifeng,
Kang Leilei,
Pan Xiaoli,
Zhong Yijun,
Hu Yong,
Ding Yunjie
Publication year - 2021
Publication title -
small
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.785
H-Index - 236
eISSN - 1613-6829
pISSN - 1613-6810
DOI - 10.1002/smll.202100372
Subject(s) - electrocatalyst , nanoclusters , x ray photoelectron spectroscopy , faraday efficiency , ammonia production , catalysis , electrochemistry , ammonia , materials science , nitrogen , redox , chemical engineering , transition metal , inorganic chemistry , nanotechnology , chemistry , electrode , metallurgy , organic chemistry , engineering
Electrocatalysts for efficient production of ammonia from nitrogen reduction reaction (NRR) under ambient conditions are attracted growing interest in recent years, which demonstrate a great potential to replace the Haber–Bosch method which suffers the problems of the huge energy consumption and massive CO 2 production. In this work, a novel electrocatalyst of Au 25 ‐Cys‐M is fabricated for NRR under ambient conditions, with transition metal ions (e.g., Mo 6+ , Fe 3+ , Co 2+ , Ni 2+ ) atomically decorated on Au 25 nanoclusters via thiol bridging. The Au 25 ‐Cys‐Mo catalyst exhibits the highest Faradaic efficiency (26.5%) and NH 3 yield (34.5 µg h −1 mg cat −1 ) in 0.1 m HCl solution. X‐ray photoelectron spectroscopy analysis and high angle annular dark field image‐scanning transmission electron microscopy characterization reveal that the electronic structure of Mo is optimized by forming the structure of Au‐S‐Mo and Mo acts as active sites for activating the nitrogen to promote the electrochemical production of ammonia. This work provides a new insight into the precise fabrication of efficient NRR electrocatalysts.