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Selective Cocatalyst Deposition on ZnTiO 3− x N y Hollow Nanospheres with Efficient Charge Separation for Solar‐Driven Overall Water Splitting
Author(s) -
Wei Shunhang,
Chang Shufang,
Qian Jun,
Xu Xiaoxiang
Publication year - 2021
Publication title -
small
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.785
H-Index - 236
eISSN - 1613-6829
pISSN - 1613-6810
DOI - 10.1002/smll.202100084
Subject(s) - photocatalysis , stoichiometry , dissociation (chemistry) , materials science , deposition (geology) , water splitting , chemical engineering , charge carrier , surface charge , nanotechnology , analytical chemistry (journal) , chemistry , optoelectronics , catalysis , chromatography , paleontology , biochemistry , sediment , engineering , biology
Pt and RhO x cocatalysts are selectively deposited at inner and outer surface of ZnTiO 3− x N y hollow nanospheres, respectively. The resulting photocatalytic systems exhibit promising activity for photocatalytic overall water splitting with stoichiometric H 2 /O 2 ratio under simulated solar insolation. Selective deposition of Pt and RhO x cocatalysts at different surfaces not only mitigates back reactions of the products but also induces strong potential gradient within nanospheres that promotes efficient dissociation and fast migration of photocarriers to the surface.