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Lithium Metal Batteries: The Synergetic Effect of Lithium Bisoxalatodifluorophosphate and Fluoroethylene Carbonate on Dendrite Suppression for Fast Charging Lithium Metal Batteries (Small 30/2020)
Author(s) -
Shi Pengcheng,
Liu Fanfan,
Feng YueZhan,
Zhou Jiafeng,
Rui Xianhong,
Yu Yan
Publication year - 2020
Publication title -
small
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.785
H-Index - 236
eISSN - 1613-6829
pISSN - 1613-6810
DOI - 10.1002/smll.202070164
Subject(s) - lithium (medication) , electrolyte , lithium metal , metal , lithium carbonate , salt (chemistry) , materials science , interphase , inorganic chemistry , dendrite (mathematics) , carbonate , conductivity , ionic conductivity , ionic bonding , chemical engineering , chemistry , electrode , ion , metallurgy , organic chemistry , medicine , genetics , geometry , mathematics , biology , engineering , endocrinology
In article number 2001989, Xianhong Rui, Yan Yu, and co‐workers develop a Li salt, lithium bisoxalatodifluorophosphate (LiDFBOP), to modify the solid‐electrolyte interphase (SEI) in fluoroethylene carbonate (FEC)–based electrolyte for lithium metal batteries. Benefiting from the synergetic effect of the LiDFBOP and FEC, a fluorinated SEI rich in LiF and Li x PO y F z species is achieved, demonstrating the improved stability and ionic conductivity for fast Li + transportation.