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Oxidative Desulfurization: Confined Heteropoly Blues in Defected Zr‐MOF (Bottle Around Ship) for High‐Efficiency Oxidative Desulfurization (Small 14/2020)
Author(s) -
Chang Xue,
Yang XianFeng,
Qiao Yang,
Wang Shuo,
Zhang MingHui,
Xu Jun,
Wang DanHong,
Bu XianHe
Publication year - 2020
Publication title -
small
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.785
H-Index - 236
eISSN - 1613-6829
pISSN - 1613-6810
DOI - 10.1002/smll.202070077
Subject(s) - flue gas desulfurization , thiophene , oxidative phosphorylation , blues , catalysis , thiourea , metal organic framework , chemistry , electrophile , materials science , organic chemistry , adsorption , art , biochemistry , art history
In article number 1906432, Dan‐Hong Wang, Xian‐He Bu, and co‐workers present a novel design strategy aiming to form heteropoly blues confined in defected Zr‐metal–organic framework (MOF), which can expose more unsaturated metal sites to promote the catalytic activity by adding thiourea. Moreover, 1‐butyl 3‐methyl imidazolium phosphomolybdate blues are also confined in Zr‐MOF to obtain higher oxidative desulfurization activity owing to the affinity between electron‐rich thiophene‐based compounds and electrophilic imidazolium compounds.