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P3/O3 Integrated Layered Oxide as High‐Power and Long‐Life Cathode toward Na‐Ion Batteries
Author(s) -
Zhang SiYuan,
Guo YuJie,
Zhou YaNan,
Zhang XuDong,
Niu YuBin,
Wang EnHui,
Huang LinBo,
An PengFei,
Zhang Jing,
Yang XinAn,
Yin YaXia,
Xu Sailong,
Guo YuGuo
Publication year - 2021
Publication title -
small
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.785
H-Index - 236
eISSN - 1613-6829
pISSN - 1613-6810
DOI - 10.1002/smll.202007236
Subject(s) - cathode , materials science , rietveld refinement , electrochemistry , oxide , ion , scanning electron microscope , transmission electron microscopy , phase (matter) , crystallography , analytical chemistry (journal) , electrode , nanotechnology , crystal structure , chemistry , metallurgy , organic chemistry , chromatography , composite material
Low‐cost and stable sodium‐layered oxides (such as P2‐ and O3‐phases) are suggested as highly promising cathode materials for Na‐ion batteries (NIBs). Biphasic hybridization, mainly involving P2/O3 and P2/P3 biphases, is typically used to boost their electrochemical performances. Herein, a P3/O3 intergrown layered oxide (Na 2/3 Ni 1/3 Mn 1/3 Ti 1/3 O 2 ) as high‐rate and long‐life cathode for NIBs via tuning the amounts of Ti substitution in Na 2/3 Ni 1/3 Mn 2/3− x Ti x O 2 ( x = 0, 1/6, 1/3, 2/3) is demonstrated. The X‐ray diffraction (XRD) Rietveld refinement and aberration‐corrected scanning transmission electron microscopy show the co‐existence of P3 and O3 phases, and density functional theory calculation corroborates the appearance of the anomalous O3 phase at the Ti substitution amount of 1/3. The P3/O3 biphasic cathode delivers an unexpected rate capability (≈88.7% of the initial capacity at a high rate of 5 C) and cycling stability (≈68.7% capacity retention after 2000 cycles at 1 C), superior to those of the sing phases P3‐Na 2/3 Ni 1/3 Mn 2/3 O 2 , P3‐Na 2/3 Ni 1/3 Mn 1/2 Ti 1/6 O 2 , and O3‐Na 2/3 Ni 1/3 Ti 2/3 O 2 . The highly reversible structural evolution of the P3/O3 integrated cathode observed by ex situ XRD, ex situ X‐ray absorption spectra, and the rapid Na + diffusion kinetics, underpin the enhancement. These results show the important role of P3/O3 biphasic hybridization in designing and engineering layered oxide cathodes for NIBs.