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Multifunctional Nickel Sulfide Nanosheet Arrays for Solar‐Intensified Oxygen Evolution Reaction
Author(s) -
Zhang Yajing,
Wang Yuchao,
Jiang Heqing,
Huang Minghua
Publication year - 2020
Publication title -
small
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.785
H-Index - 236
eISSN - 1613-6829
pISSN - 1613-6810
DOI - 10.1002/smll.202002550
Subject(s) - oxygen evolution , nanosheet , tafel equation , materials science , photothermal therapy , water splitting , electrochemistry , overpotential , nickel , chemical engineering , bifunctional , nickel sulfide , hydrogen production , nanotechnology , electrode , catalysis , photocatalysis , chemistry , metallurgy , engineering , biochemistry
Electrochemical water splitting for hydrogen production is currently hindered by the sluggish kinetic of anodic oxygen evolution reaction (OER). By integrating photothermal materials into electrocatalytic network and thus allowing solar energy to work as additional driving force, the OER is expected to be boosted. However, the rational design of such electrochemical system still remains a challenge due to the spatial inconsistency between photothermal component and electrocatalytic component. Herein, it is reported that multifunctional nickel sulfide (Ni 3 S 2 ) nanosheet arrays show both photothermal and electrocatalytic properties for solar‐intensified electrocatalytic system, which well eliminates the spatial inconsistency between the aforementioned two types of functional components by using one bifunctional material. The deliberate design of nanoarray architecture formed by the interconnected Ni 3 S 2 nanosheets endows larger surface area and higher surface roughness, thus enhancing light absorption by suppressing diffuse reflection and facilitating electron transfer in electrocatalytic reactions. Therefore, the OER activity is significantly improved. Under light illumination, the current density of Ni 3 S 2 nanosheets could reach 492.2 mA cm −2 at 1.55 V, about 2.5‐fold that in dark conditions, with a Tafel slope of as low as 60 dec −1 . The solar‐intensified electrochemical system based on multifunctional material presents prospective potential in electrochemical water splitting for efficient hydrogen production.