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Slower Removing Ligands of Metal Organic Frameworks Enables Higher Electrocatalytic Performance of Derived Nanomaterials
Author(s) -
Hu Qi,
Huang Xiaowan,
Wang Ziyu,
Li Guomin,
Han Zhen,
Yang Hengpan,
Liao Peng,
Ren XiangZhong,
Zhang Qianling,
Liu Jianhong,
He Chuanxin
Publication year - 2020
Publication title -
small
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.785
H-Index - 236
eISSN - 1613-6829
pISSN - 1613-6810
DOI - 10.1002/smll.202002210
Subject(s) - bimetallic strip , prussian blue , nanomaterials , pyrolysis , oxygen evolution , nanoparticle , oxygen , metal , metal organic framework , chemical engineering , materials science , chemistry , nanotechnology , inorganic chemistry , electrochemistry , adsorption , organic chemistry , electrode , engineering
The widely used route of high‐temperature pyrolysis for transformation of Prussian blue analogs (PBAs) to functional nanomaterials leads to the fast removal of CN − ligands, and thus the formation of large metal aggregates and the loss of porous structures inside PBAs. Here, a controllable pyrolysis route at low temperature is reported for retaining the confined effect of CN − ligands to metal cations during the whole pyrolysis process, thereby preparing high‐surface‐area cubes comprising disordered bimetallic oxides (i.e., Co 3 O 4 and Fe 2 O 3 ) nanoparticles. The disordered structure of Co 3 O 4 enables the exposure of abundant oxygen vacancies. Notably, for the first time, it is found that the in situ generated CoOOH during the oxygen evolution reaction (OER) can inherit the oxygen vacancies of pristine Co 3 O 4 (i.e., before OER), and such CoOOH with abundant oxygen vacancies adsorbs two − OH in the following Co 3+ to Co 4+ for markedly promoting OER. However, during the similar step, the ordered Co 3 O 4 with less oxygen vacancies only involves one − OH, resulting in the additional overpotentials for adsorbing − OH. Consequently, with high surface area and disordered Co 3 O 4 , the as‐synthesized electrocatalysts have a low potential of 237 mV at 10 mA cm −2 , surpassing most of reported electrocatalysts.