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Hierarchical 3D Oxygenated Cobalt Molybdenum Selenide Nanosheets as Robust Trifunctional Catalyst for Water Splitting and Zinc–Air Batteries
Author(s) -
Prabhakaran Sampath,
Balamurugan Jayaraman,
Kim Nam Hoon,
Lee Joong Hee
Publication year - 2020
Publication title -
small
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.785
H-Index - 236
eISSN - 1613-6829
pISSN - 1613-6810
DOI - 10.1002/smll.202000797
Subject(s) - overpotential , water splitting , materials science , selenide , oxygen evolution , catalysis , bimetallic strip , cobalt , nanoporous , chemical engineering , faraday efficiency , anode , nanotechnology , electrochemistry , inorganic chemistry , electrode , chemistry , organic chemistry , metallurgy , photocatalysis , selenium , engineering
The development of hierarchical nanostructures with highly active and durable multifunctional catalysts has a new significance in the context of new energy technologies of water splitting and metal–air batteries. Herein, a strategy is demonstrated to construct a 3D hierarchical oxygenated cobalt molybdenum selenide (O‐Co 1− x Mo x Se 2 ) series with attractive nanoarchitectures, which are fabricated by a simple and cost‐effective hydrothermal process followed by an exclusive ion‐exchange process. Owing to its highly electroactive sites with numerous nanoporous networks and plentiful oxygen vacancies, the optimal O‐Co 0.5 Mo 0.5 Se 2 could catalyze the hydrogen evolution reaction and oxygen evolution reaction effectively with a low overpotential of ≈102 and 189 mV, at a current density of 10 mA cm −2 , respectively, and exceptional durability. Most importantly, the O‐Co 0.5 Mo 0.5 Se 2 ||O‐Co 0.5 Mo 0.5 Se 2 water splitting device only entails a voltage of ≈1.53 V at a current density of 10 mA cm −2 , which is much better than benchmark Pt/C||RuO 2 (≈1.56 V). Furthermore, O‐Co 0.5 Mo 0.5 Se 2 air cathode‐based zinc–air batteries exhibit an excellent power density of 120.28 mW cm −2 and exceptional cycling stability for 60 h, superior to those of state‐of‐art Pt/C+RuO 2 pair‐based zinc–air batteries. The present study provides a strategy to design hierarchical 3D oxygenated bimetallic selenide‐based multifunctional catalysts for energy conversion and storage systems.