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B,N Codoped Graphitic Nanotubes Loaded with Co Nanoparticles as Superior Sulfur Host for Advanced Li–S Batteries
Author(s) -
Wang Zhuosen,
Shen Jiadong,
Ji Shaomin,
Xu Xijun,
Zuo Shiyong,
Liu Zhengbo,
Zhang Dechao,
Hu Renzong,
Ouyang Liuzhang,
Liu Jun,
Zhu Min
Publication year - 2020
Publication title -
small
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.785
H-Index - 236
eISSN - 1613-6829
pISSN - 1613-6810
DOI - 10.1002/smll.201906634
Subject(s) - sulfur , nanoparticle , materials science , electrochemistry , cathode , carbon nanotube , chemical engineering , conductivity , lithium (medication) , redox , electrode , anode , nanotechnology , chemistry , metallurgy , endocrinology , engineering , medicine
Lithium–sulfur batteries (LSBs) are considered as one of the best candidates for novel rechargeable batteries due to their high energy densities and abundant required materials. However, the poor conductivity and large volume expansion of sulfur and the “shuttle effect” of lithium polysulfides (LPSs) have significantly hindered the development and successful commercialization of LSBs. Bean‐like B,N codoped carbon nanotubes loaded with Co nanoparticles (Co@BNTs), which can act as advanced sulfur hosts for the novel LSB cathode, are fabricated. Uniform graphitic nanotubes improve the conductivity of the electrode and load more electroactive sulfur and buffer volume expansion during the electrochemical reaction. In addition, loaded Co nanoparticles and codoped B,N sites can significantly suppress the “shuttle effect” of LPSs with strong chemical interaction. It is established that the Co nanoparticles and codoped B,N can provide more active sites to catalyze the redox reaction of sulfur cathode. This stable Co@BNTs‐S cathode displays an exceptional electrochemical performance (1160 mA h g −1 after 200 cycles at 0.1 C) and outstanding stable cycle performance (1008 mA h g −1 after 400 cycles at 1.0 C with an extremely low attenuation rate of 0.038% per cycle).