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Oxygen Vacancy–Rich In‐Doped CoO/CoP Heterostructure as an Effective Air Cathode for Rechargeable Zn–Air Batteries
Author(s) -
Jin Wei,
Chen Jianping,
Liu Bing,
Hu Jiugang,
Wu Zexing,
Cai Weiquan,
Fu Gengtao
Publication year - 2019
Publication title -
small
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.785
H-Index - 236
eISSN - 1613-6829
pISSN - 1613-6810
DOI - 10.1002/smll.201904210
Subject(s) - electrocatalyst , overpotential , materials science , cathode , oxygen , heterojunction , oxygen evolution , chemical engineering , bifunctional , nanotechnology , catalysis , optoelectronics , chemistry , electrode , electrochemistry , biochemistry , organic chemistry , engineering
An efficient and low‐cost electrocatalyst for reversible oxygen electrocatalysis is crucial for improving the performance of rechargeable metal−air batteries. Herein, a novel oxygen vacancy–rich 2D porous In‐doped CoO/CoP heterostructure (In‐CoO/CoP FNS) is designed and developed by a facile free radicals–induced strategy as an effective bifunctional electrocatalyst for rechargeable Zn–air batteries. The electron spin resonance and X‐ray absorption near edge spectroscopy provide clear evidence that abundant oxygen vacancies are formed in the interface of In‐CoO/CoP FNS. Owing to abundant oxygen vacancies, porous heterostructure, and multiple components, In‐CoO/CoP FNS exhibits excellent oxygen reduction reaction activity with a positive half‐wave potential of 0.81 V and superior oxygen evolution reaction activity with a low overpotential of 365 mV at 10 mA cm −2 . Moreover, a home‐made Zn–air battery with In‐CoO/CoP FNS as an air cathode delivers a large power density of 139.4 mW cm −2 , a high energy density of 938 Wh kg Zn −1 , and can be steadily cycled over 130 h at 10 mA cm −2 , demonstrating great application potential in rechargeable metal–air batteries.