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Self‐Regulated Smectic Emulsion with Switchable Lasing Application
Author(s) -
Kim Dae Seok,
Lee Wonsuk,
LopezLeon Teresa,
Yoon Dong Ki
Publication year - 2019
Publication title -
small
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.785
H-Index - 236
eISSN - 1613-6829
pISSN - 1613-6810
DOI - 10.1002/smll.201903818
Subject(s) - emulsion , materials science , microfluidics , dispersity , liquid crystal , lasing threshold , polymer , molecule , nanotechnology , chemical engineering , silicon , organic chemistry , polymer chemistry , optoelectronics , chemistry , composite material , wavelength , engineering
A structurally reversible smectic liquid crystal (LC) emulsion made of semifluorinated rod‐type molecules in silicon oil, which is controlled by simple heating and cooling, is presented. Without adding any kind of additives, such as surfactants, polymers or emulsifiers, and without using any special tools, such as microfluidics or gas bubbling, the LC molecules spontaneously form monodisperse spherical and myelin‐like structures upon cooling from the isotropic temperature. The LC emulsion can easily trap guest materials, providing a platform for repeatable and reliable switchable emulsification. For example, this interesting system enables the realization of an on–off lasing system by confining fluorescent dyes in the LC droplets.