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S‐Doped Carbon Fibers Uniformly Embedded with Ultrasmall TiO 2 for Na + /Li + Storage with High Capacity and Long‐Time Stability
Author(s) -
Chen Changmiao,
Li Pengchao,
Wang Taihong,
Wang Shuangyin,
Zhang Ming
Publication year - 2019
Publication title -
small
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.785
H-Index - 236
eISSN - 1613-6829
pISSN - 1613-6810
DOI - 10.1002/smll.201902201
Subject(s) - materials science , anode , carbon fibers , carbon nanofiber , energy storage , heteroatom , nanoparticle , nanotechnology , microporous material , electrochemistry , chemical engineering , doping , battery (electricity) , lithium (medication) , nanofiber , composite material , optoelectronics , electrode , chemistry , carbon nanotube , organic chemistry , composite number , medicine , ring (chemistry) , power (physics) , physics , quantum mechanics , endocrinology , engineering
Building a rechargeable battery with high capacity, high energy density, and long lifetime contributes to the development of novel energy storage devices in the future. Although carbon materials are very attractive anode materials for lithium‐ion batteries (LIBs), they present several deficiencies when used in sodium‐ion batteries (SIBs). The choice of an appropriate structural design and heteroatom doping are critical steps to improve the capacity and stability. Here, carbon‐based nanofibers are produced by sulfur doping and via the introduction of ultrasmall TiO 2 nanoparticles into the carbon fibers (CNF‐S@TiO 2 ). It is discovered that the introduction of TiO 2 into carbon nanofibers can significantly improve the specific surface area and microporous volume for carbon materials. The TiO 2 content is controlled to obtain CNF‐S@TiO 2 ‐5 to use as the anode material for SIBs/LIBs with enhanced electrochemical performance in Na + /Li + storage. During the charge/discharge process, the S‐doping and the incorporation of TiO 2 nanoparticles into carbon fibers promote the insertion/extraction of the ions and enhance the capacity and cycle life. The capacity of CNF‐S@TiO 2 ‐5 can be maintained at ≈300 mAh g −1 over 600 cycles at 2 A g −1 in SIBs. Moreover, the capacity retention of such devices is 94%, showing high capacity and good stability.