Premium
Efficient Nitrogen‐Doped Carbon for Zinc–Bromine Flow Battery
Author(s) -
Xiang HongXin,
Tan AiDong,
Piao JinHua,
Fu ZhiYong,
Liang ZhenXing
Publication year - 2019
Publication title -
small
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.785
H-Index - 236
eISSN - 1613-6829
pISSN - 1613-6810
DOI - 10.1002/smll.201901848
Subject(s) - flow battery , heteroatom , materials science , battery (electricity) , carbonization , carbon fibers , bromine , chemical engineering , zinc , energy storage , faraday efficiency , electrode , electrochemistry , inorganic chemistry , nitrogen , conductivity , doping , chemistry , organic chemistry , composite material , metallurgy , alkyl , optoelectronics , scanning electron microscope , composite number , power (physics) , physics , quantum mechanics , engineering , electrolyte
The zinc–bromine flow battery (ZBFB) is one of the most promising technologies for large‐scale energy storage. Here, nitrogen‐doped carbon is synthesized and investigated as the positive electrode material in ZBFBs. The synthesis includes the carbonization of the glucose precursor and nitrogen doping by etching in ammonia gas. Physicochemical characterizations reveal that the resultant carbon exhibits high electronic conductivity, large specific surface area, and abundant heteroatom‐containing functional groups, which benefit the formation and exposure of the active sites toward the Br 2 /Br − redox couple. As a result, the assembled ZBFB achieves a voltage efficiency of 83.0% and an energy efficiency of 82.5% at a current density of 80 mA cm −2 , which are among the top values in literature. Finally, the ZBFB does not yield any detectable degradation in performance after a 200‐cycle charging/discharging test, revealing its high stability. In summary, this work provides a highly efficient electrode material for the zinc–bromine flow battery.