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Nitrogen‐Doped Graphene‐Encapsulated Nickel–Copper Alloy Nanoflower for Highly Efficient Electrochemical Hydrogen Evolution Reaction
Author(s) -
Liu Bin,
Peng HuiQing,
Cheng Junye,
Zhang Kui,
Chen Da,
Shen Dong,
Wu Shuilin,
Jiao Tianpeng,
Kong Xin,
Gao Qili,
Bu Shuyu,
Lee ChunSing,
Zhang Wenjun
Publication year - 2019
Publication title -
small
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.785
H-Index - 236
eISSN - 1613-6829
pISSN - 1613-6810
DOI - 10.1002/smll.201901545
Subject(s) - tafel equation , overpotential , materials science , electrocatalyst , graphene , nanoflower , chemical engineering , nickel , copper , inorganic chemistry , electrochemistry , nanotechnology , metallurgy , electrode , chemistry , nanostructure , engineering
Abstract Development of high‐performance and low‐cost nonprecious metal electrocatalysts is critical for eco‐friendly hydrogen production through electrolysis. Herein, a novel nanoflower‐like electrocatalyst comprising few‐layer nitrogen‐doped graphene‐encapsulated nickel–copper alloy directly on a porous nitrogen‐doped graphic carbon framework (denoted as Ni x Cu y @ NG‐NC) is successfully synthesized using a facile and scalable method through calcinating the carbon, copper, and nickel hydroxy carbonate composite under inert atmosphere. The introduction of Cu can effectively modulate the morphologies and hydrogen evolution reaction (HER) performance. Moreover, the calcination temperature is an important factor to tune the thickness of graphene layers of the Ni x Cu y @ NG‐NC composites and the associated electrocatalytic performance. Due to the collective effects including unique porous flowered architecture and the synergetic effect between the bimetallic alloy core and graphene shell, the Ni 3 Cu 1 @ NG‐NC electrocatalyst obtained under optimized conditions exhibits highly efficient and ultrastable activity toward HER in harsh environments, i.e., a low overpotential of 122 mV to achieve a current density of 10 mA cm −2 with a low Tafel slope of 84.2 mV dec −1 in alkaline media, and a low overpotential of 95 mV to achieve a current density of 10 mA cm −2 with a low Tafel slope of 77.1 mV dec −1 in acidic electrolyte.