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Ultrathin, Core–Shell Structured SiO 2 Coated Mn 2+ ‐Doped Perovskite Quantum Dots for Bright White Light‐Emitting Diodes
Author(s) -
Tang Xiaosheng,
Chen Weiwei,
Liu Zhengzheng,
Du Juan,
Yao Zhiqiang,
Huang Yi,
Chen Cheng,
Yang Zhaoqi,
Shi Tongchao,
Hu Wei,
Zang Zhigang,
Chen Yu,
Leng Yuxin
Publication year - 2019
Publication title -
small
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.785
H-Index - 236
eISSN - 1613-6829
pISSN - 1613-6810
DOI - 10.1002/smll.201900484
Subject(s) - quantum dot , materials science , perovskite (structure) , white light , diode , light emitting diode , optoelectronics , doping , core (optical fiber) , shell (structure) , luminescence , crystallography , chemistry , composite material
All‐inorganic semiconductor perovskite quantum dots (QDs) with outstanding optoelectronic properties have already been extensively investigated and implemented in various applications. However, great challenges exist for the fabrication of nanodevices including toxicity, fast anion‐exchange reactions, and unsatisfactory stability. Here, the ultrathin, core–shell structured SiO 2 coated Mn 2+ doped CsPbX 3 (X = Br, Cl) QDs are prepared via one facile reverse microemulsion method at room temperature. By incorporation of a multibranched capping ligand of trioctylphosphine oxide, it is found that the breakage of the CsPbMnX 3 core QDs contributed from the hydrolysis of silane could be effectively blocked. The thickness of silica shell can be well‐controlled within 2 nm, which gives the CsPbMnX 3 @SiO 2 QDs a high quantum yield of 50.5% and improves thermostability and water resistance. Moreover, the mixture of CsPbBr 3 QDs with green emission and CsPbMnX 3 @SiO 2 QDs with yellow emission presents no ion exchange effect and provides white light emission. As a result, a white light‐emitting diode (LED) is successfully prepared by the combination of a blue on‐chip LED device and the above perovskite mixture. The as‐prepared white LED displays a high luminous efficiency of 68.4 lm W −1 and a high color‐rendering index of Ra = 91, demonstrating their broad future applications in solid‐state lighting fields.