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Nickel@Nitrogen‐Doped Carbon@MoS 2 Nanosheets: An Efficient Electrocatalyst for Hydrogen Evolution Reaction
Author(s) -
Shah Sayyar Ali,
Shen Xiaoping,
Xie Minghua,
Zhu Guoxing,
Ji Zhenyuan,
Zhou Hongbo,
Xu Keqiang,
Yue Xiaoyang,
Yuan Aihua,
Zhu Jun,
Chen Yao
Publication year - 2019
Publication title -
small
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.785
H-Index - 236
eISSN - 1613-6829
pISSN - 1613-6810
DOI - 10.1002/smll.201804545
Subject(s) - overpotential , electrocatalyst , tafel equation , materials science , molybdenum disulfide , catalysis , nickel , chemical engineering , hydrogen production , carbon fibers , water splitting , substrate (aquarium) , nanotechnology , inorganic chemistry , chemistry , electrochemistry , metallurgy , composite material , electrode , photocatalysis , organic chemistry , composite number , engineering , oceanography , geology
Abstract Developing cheap, abundant, and easily available electrocatalysts to drive the hydrogen evolution reaction (HER) at small overpotentials is an urgent demand of hydrogen production from water splitting. Molybdenum disulfide (MoS 2 ) based composites have emerged as competitive electrocatalysts for HER in recent years. Herein, nickel@nitrogen‐doped carbon@MoS 2 nanosheets (Ni@NC@MoS 2 ) hybrid sub‐microspheres are presented as HER catalyst. MoS 2 nanosheets with expanded interlayer spacings are vertically grown on nickel@nitrogen‐doped carbon (Ni@NC) substrate to form Ni@NC@MoS 2 hierarchical sub‐microspheres by a simple hydrothermal process. The formed Ni@NC@MoS 2 composites display excellent electrocatalytic activity for HER with an onset overpotential of 18 mV, a low overpotential of 82 mV at 10 mA cm −2 , a small Tafel slope of 47.5 mV dec −1 , and high durability in 0.5 H 2 SO 4 solution. The outstanding HER performance of the Ni@NC@MoS 2 catalyst can be ascribed to the synergistic effect of dense catalytic sites on MoS 2 nanosheets with exposed edges and expanded interlayer spacings, and the rapid electron transfer from Ni@NC substrate to MoS 2 nanosheets. The excellent Ni@NC@MoS 2 electrocatalyst promises potential application in practical hydrogen production, and the strategy reported here can also be extended to grow MoS 2 on other nitrogen‐doped carbon encapsulated metal species for various applications.