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Hysteresis‐Free 1D Network Mixed Halide‐Perovskite Semitransparent Solar Cells
Author(s) -
Ka Ibrahima,
Asuo Ivy M.,
Basu Suchismita,
Fourmont Paul,
Gedamu Dawit M.,
Pignolet Alain,
Cloutier Sylvain G.,
Nechache Riad
Publication year - 2018
Publication title -
small
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.785
H-Index - 236
eISSN - 1613-6829
pISSN - 1613-6810
DOI - 10.1002/smll.201802319
Subject(s) - materials science , perovskite (structure) , hysteresis , photocurrent , solution process , microstructure , chemical engineering , thin film , solar cell , energy conversion efficiency , grain size , perovskite solar cell , nanotechnology , optoelectronics , composite material , physics , quantum mechanics , engineering
The morphology of hybrid organic–inorganic perovskite films is known to strongly affect the performance of perovskite‐based solar cells. CH 3 NH 3 PbI 3‐x Cl x (MAPbI 3‐x Cl x ) films have been previously fabricated with 100% surface coverage in glove boxes. In ambient air, fabrication generally relies on solvent engineering to obtain compact films. In contrast, this work explores the potential of altering the perovskites microstructure for solar cell engineering. This work starts with CH 3 NH 3 PbI 3‐ x Cl x , films with grain morphology carefully controlled by varying the deposition speed during the spin‐coating process to fabricate efficient and partially transparent solar cells. Devices produced with a CH 3 NH 3 PbI 3‐ x Cl x film and a compact thick top gold electrode reach a maximum efficiency of 10.2% but display a large photocurrent hysteresis. As it is demonstrated, the introduction of different concentrations of bromide in the precursor solution addresses the hysteresis issues and turns the film morphology into a partially transparent interconnected network of 1D microstructures. This approach leads to semitransparent solar cells with negligible hysteresis and efficiencies up to 7.2%, while allowing average transmission of 17% across the visible spectrum. This work demonstrates that the optimization of the perovskites composition can mitigate the hysteresis effects commonly attributed to the charge trapping within the perovskite film.