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Patterning Hydrophobic Surfaces by Negative Microcontact Printing and Its Applications
Author(s) -
Wu Han,
Wu Liang,
Zhou Xiaohu,
Liu Baishu,
Zheng Bo
Publication year - 2018
Publication title -
small
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.785
H-Index - 236
eISSN - 1613-6829
pISSN - 1613-6810
DOI - 10.1002/smll.201802128
Subject(s) - microcontact printing , polydimethylsiloxane , materials science , pdms stamp , nanotechnology , dewetting , contact angle , micropatterning , fabrication , thin film , composite material , medicine , alternative medicine , pathology
Here, a negative microcontact printing method is developed to form hydrophilic polydopamine (PDA) patterns with micrometer resolution on hydrophobic including perfluorinated surfaces. In the process of the negative microcontact printing, a uniform PDA thin film is first formed on the hydrophobic surface. An activated polydimethylsiloxane (PDMS) stamp is then placed in contact with the PDA‐coated hydrophobic surface. Taking advantage of the difference in the surface energy between the hydrophobic surface and the stamp, PDA is removed from the contact area after the stamp release. As a result, a PDA pattern complementary to the stamp is obtained on the hydrophobic surface. By using the negative microcontact printing, arrays of liquid droplets and single cells are reliably formed on perfluorinated surfaces. Microlens array with tunable focal length for imaging studies is further created based on the droplet array. The negative microcontact printing method is expected to be widely applicable in high‐throughput chemical and biological screening and analysis.