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Cobalt Phosphide Composite Encapsulated within N,P‐Doped Carbon Nanotubes for Synergistic Oxygen Evolution
Author(s) -
Li Hui,
Xu SiMin,
Yan Hong,
Yang Lan,
Xu Sailong
Publication year - 2018
Publication title -
small
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.785
H-Index - 236
eISSN - 1613-6829
pISSN - 1613-6810
DOI - 10.1002/smll.201800367
Subject(s) - overpotential , electrocatalyst , materials science , oxygen evolution , phosphide , chemical engineering , carbon nanotube , nanoparticle , ternary operation , nanotechnology , electrode , electrochemistry , chemistry , metal , computer science , metallurgy , programming language , engineering
Exploring highly efficient and stable oxygen evolution reaction (OER) electrocatalysts such as transition‐metal phosphides (TMPs) is critical to advancing renewable hydrogen fuel. TMP nanostructures typically involving binary or ternary TMPs tuned by cation or anion doping are suggested to be promising low‐cost and durable OER catalysts. Herein, the preparation of CoP/CoP 2 composite nanoparticles encapsulated within N,P‐doped carbon nanotubes (CoP/CoP 2 @NPCNTs) is demonstrated as a synergistic electrocatalyst for OER via the calcination of a CoAl‐layered double hydroxide/melamine mixture and subsequent phosphorization. Facile visualization by scanning electron microscopy in conjunction with electron backscatter diffraction demonstrates the encapsulation of the CoP/CoP 2 nanoparticles within the N,P‐codoped CNTs. Electrocatalytic evaluation shows that the composite electrode requires a low overpotential of 300 mV for the OER at 10 mA cm −2 in a 1.0 m KOH solution and, in particular, exhibits an excellent long‐term durability of ≈100 h, which is superior to that of the state‐of‐the‐art RuO 2 electrocatalyst. Density functional theory calculations reveal that the synergistic effect of CoP and CoP 2 can enhance the electrocatalytic performance. In addition, molecular dynamics simulations demonstrate that the generated O 2 molecules can readily diffuse out of the CNTs. Both the effects give rise to the observed OER enhancement.