Supramolecular Polymers: Flexible Chirality in Self‐Assembled  N ‐Annulated Perylenedicarboxamides (Small 20/2017) | Zendy

Buendía Julia | Zendy; Calbo Joaquín | Zendy; Ortí Enrique | Zendy; Sánchez Luis | Zendy

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Supramolecular Polymers: Flexible Chirality in Self‐Assembled N ‐Annulated Perylenedicarboxamides (Small 20/2017)

Author(s) -

Buendía Julia,

Calbo Joaquín,

Ortí Enrique,

Sánchez Luis

Publication year - 2017

Publication title -

small

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 3.785

H-Index - 236

eISSN - 1613-6829

pISSN - 1613-6810

DOI - 10.1002/smll.201770109

Subject(s) - supramolecular chemistry , chirality (physics) , circular dichroism , supramolecular chirality , helicity , supramolecular polymers , materials science , polymer , polymerization , self assembly , nanotechnology , crystallography , bundle , anisotropy , chemistry , physics , optics , crystal structure , composite material , chiral symmetry breaking , particle physics , quantum mechanics , nambu–jona lasinio model , quark

Chirality constitutes a source of inspiration for scientists. The oscillating helicity detected for the supramolecular polymers formed by the self‐assembly of three N‐annulated perylenedicarboxamides is described in article number 1603880 , by Enrique Ortí, and Luis Sánchez, and co‐workers. The cooperative supramolecular polymerization of these compounds generates helical, chiral supramolecular structures, which bundle into nanofibrillar structures to afford a highly anisotropic environment. The flexible circular dichroism behavior shown by these self‐assembling units can be utilized for the spectroscopic visualization of the torsional flows generated in a vortex.

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