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Graphene Scroll‐Coated α‐MnO 2 Nanowires as High‐Performance Cathode Materials for Aqueous Zn‐Ion Battery
Author(s) -
Wu Buke,
Zhang Guobin,
Yan Mengyu,
Xiong Tengfei,
He Pan,
He Liang,
Xu Xu,
Mai Liqiang
Publication year - 2018
Publication title -
small
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.785
H-Index - 236
eISSN - 1613-6829
pISSN - 1613-6810
DOI - 10.1002/smll.201703850
Subject(s) - cathode , materials science , graphene , battery (electricity) , dissolution , chemical engineering , x ray photoelectron spectroscopy , aqueous solution , oxide , inorganic chemistry , nanotechnology , metallurgy , chemistry , power (physics) , physics , quantum mechanics , engineering
The development of manganese dioxide as the cathode for aqueous Zn‐ion battery (ZIB) is limited by the rapid capacity fading and material dissolution. Here, a highly reversible aqueous ZIB using graphene scroll‐coated α‐MnO 2 as the cathode is proposed. The graphene scroll is uniformly coated on the MnO 2 nanowire with an average width of 5 nm, which increases the electrical conductivity of the MnO 2 nanowire and relieves the dissolution of the cathode material during cycling. An energy density of 406.6 Wh kg −1 (382.2 mA h g −1 ) at 0.3 A g −1 can be reached, which is the highest specific energy value among all the cathode materials for aqueous Zn‐ion battery so far, and good long‐term cycling stability with 94% capacity retention after 3000 cycles at 3 A g −1 are achieved. Meanwhile, a two‐step intercalation mechanism that Zn ions first insert into the layers and then the tunnels of MnO 2 framework is proved by in situ X‐ray diffraction, galvanostatic intermittent titration technique, and X‐ray photoelectron spectroscopy characterizations. The graphene scroll‐coated metallic oxide strategy can also bring intensive interests for other energy storage systems.