Recent Advances in Layered Ti 3 C 2 T x MXene for Electrochemical Energy Storage

Ti 3 C 2 T x , a typical representative among the emerging family of 2D layered transition metal carbides and/or nitrides referred to as MXenes, has exhibited multiple advantages including metallic conductivity, a plastic layer structure, small band gaps, and the hydrophilic nature of its functionalized surface. As a result, this 2D material is intensively investigated for application in the energy storage field. The composition, morphology and texture, surface chemistry, and structural configuration of Ti 3 C 2 T x directly influence its electrochemical performance, e.g., the use of a well‐designed 2D Ti 3 C 2 T x as a rechargeable battery anode has significantly enhanced battery performance by providing more chemically active interfaces, shortened ion‐diffusion lengths, and improved in‐plane carrier/charge‐transport kinetics. Some recent progresses of Ti 3 C 2 T x MXene are achieved in energy storage. This Review summarizes recent advances in the synthesis and electrochemical energy storage applications of Ti 3 C 2 T x MXene including supercapacitors, lithium‐ion batteries, sodium‐ion batteries, and lithium–sulfur batteries. The current opportunities and future challenges of Ti 3 C 2 T x MXene are addressed for energy‐storage devices. This Review seeks to provide a rational and in‐depth understanding of the relation between the electrochemical performance and the nanostructural/chemical composition of Ti 3 C 2 T x , which will promote the further development of 2D MXenes in energy‐storage applications.