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Porous Carbon‐Hosted Atomically Dispersed Iron–Nitrogen Moiety as Enhanced Electrocatalysts for Oxygen Reduction Reaction in a Wide Range of pH
Author(s) -
Fu Shaofang,
Zhu Chengzhou,
Su Dong,
Song Junhua,
Yao Siyu,
Feng Shuo,
Engelhard Mark H.,
Du Dan,
Lin Yuehe
Publication year - 2018
Publication title -
small
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.785
H-Index - 236
eISSN - 1613-6829
pISSN - 1613-6810
DOI - 10.1002/smll.201703118
Subject(s) - oxygen reduction reaction , carbon fibers , materials science , nitrogen , oxygen , porosity , chemical engineering , electrocatalyst , oxygen reduction , moiety , inorganic chemistry , nanotechnology , chemistry , electrode , electrochemistry , organic chemistry , composite material , composite number , engineering
As one of the alternatives to replace precious metal catalysts, transition‐metal–nitrogen–carbon (M–N–C) electrocatalysts have attracted great research interest due to their low cost and good catalytic activities. Despite nanostructured M–N–C catalysts can achieve good electrochemical performances, they are vulnerable to aggregation and insufficient catalytic sites upon continuous catalytic reaction. In this work, metal–organic frameworks derived porous single‐atom electrocatalysts (SAEs) were successfully prepared by simple pyrolysis procedure without any further posttreatment. Combining the X‐ray absorption near‐edge spectroscopy and electrochemical measurements, the SAEs have been identified with superior oxygen reduction reaction (ORR) activity and stability compared with Pt/C catalysts in alkaline condition. More impressively, the SAEs also show excellent ORR electrocatalytic performance in both acid and neutral media. This study of nonprecious catalysts provides new insights on nanoengineering catalytically active sites and porous structures for nonprecious metal ORR catalysis in a wide range of pH.