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Ultrathin Nanosheet Assembled Sn 0.91 Co 0.19 S 2 Nanocages with Exposed (100) Facets for High‐Performance Lithium‐Ion Batteries
Author(s) -
Li Bing,
Gu Peng,
Zhang Guangxun,
Lu Yao,
Huang Kesheng,
Xue Huaiguo,
Pang Huan
Publication year - 2018
Publication title -
small
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.785
H-Index - 236
eISSN - 1613-6829
pISSN - 1613-6810
DOI - 10.1002/smll.201702184
Subject(s) - nanocages , nanosheet , materials science , lithium (medication) , electrochemistry , electrode , nanotechnology , nanomaterials , chemical engineering , ion , doping , optoelectronics , catalysis , chemistry , medicine , biochemistry , organic chemistry , endocrinology , engineering
Ultrathin 2D inorganic nanomaterials are good candidates for lithium‐ion batteries, as well as the micro/nanocage structures with unique and tunable morphologies. Meanwhile, as a cost‐effective method, chemical doping plays a vital role in manipulating physical and chemical properties of metal oxides and sulfides. Thus, the design of ultrathin, hollow, and chemical doped metal sulfides shows great promise for the application of Li‐ion batteries by shortening the diffusion pathway of Li ions as well as minimizing the electrode volume change. Herein, ultrathin nanosheet assembled Sn 0.91 Co 0.19 S 2 nanocages with exposed (100) facets are first synthesized. The as‐prepared electrode delivers an excellent discharge capacity of 809 mA h g −1 at a current density of 100 mA g −1 with a 91% retention after 60 discharge–charge cycles. The electrochemical performance reveals that the Li‐ion batteries prepared by Sn 0.91 Co 0.19 S 2 nanocages have high capacity and great cycling stability.