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Mesoporous NiS 2 Nanospheres Anode with Pseudocapacitance for High‐Rate and Long‐Life Sodium‐Ion Battery
Author(s) -
Sun Ruimin,
Liu Sijie,
Wei Qiulong,
Sheng Jinzhi,
Zhu Shaohua,
An Qinyou,
Mai Liqiang
Publication year - 2017
Publication title -
small
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.785
H-Index - 236
eISSN - 1613-6829
pISSN - 1613-6810
DOI - 10.1002/smll.201701744
Subject(s) - pseudocapacitance , materials science , anode , mesoporous material , electrochemistry , chemical engineering , nanotechnology , battery (electricity) , electrode , supercapacitor , catalysis , chemistry , power (physics) , biochemistry , physics , quantum mechanics , engineering
It is of great importance to exploit electrode materials for sodium‐ion batteries (SIBs) with low cost, long life, and high‐rate capability. However, achieving quick charge and high power density is still a major challenge for most SIBs electrodes because of the sluggish sodiation kinetics. Herein, uniform and mesoporous NiS 2 nanospheres are synthesized via a facile one‐step polyvinylpyrrolidone assisted method. By controlling the voltage window, the mesoporous NiS 2 nanospheres present excellent electrochemical performance in SIBs. It delivers a high reversible specific capacity of 692 mA h g −1 . The NiS 2 anode also exhibits excellent high‐rate capability (253 mA h g −1 at 5 A g −1 ) and long‐term cycling performance (319 mA h g −1 capacity remained even after 1000 cycles at 0.5 A g −1 ). A dominant pseudocapacitance contribution is identified and verified by kinetics analysis. In addition, the amorphization and conversion reactions during the electrochemical process of the mesoporous NiS 2 nanospheres is also investigated by in situ X‐ray diffraction. The impressive electrochemical performance reveals that the NiS 2 offers great potential toward the development of next generation large scale energy storage.