Enantiomeric Nanostructures: Chiral Nanostructures from Helical Copolymer–Metal Complexes: Tunable Cation–π Interactions and Sergeants and Soldiers Effect (Small 2/2016) | Zendy

Arias Sandra | Zendy; Bergueiro Julián | Zendy; Freire Félix | Zendy; Quiñoá Emilio | Zendy; Riguera Ricardo | Zendy

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Enantiomeric Nanostructures: Chiral Nanostructures from Helical Copolymer–Metal Complexes: Tunable Cation–π Interactions and Sergeants and Soldiers Effect (Small 2/2016)

Author(s) -

Arias Sandra,

Bergueiro Julián,

Freire Félix,

Quiñoá Emilio,

Riguera Ricardo

Publication year - 2016

Publication title -

small

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 3.785

H-Index - 236

eISSN - 1613-6829

pISSN - 1613-6810

DOI - 10.1002/smll.201670009

Subject(s) - copolymer , nanostructure , supramolecular chemistry , materials science , monomer , enantiomer , solvent , chirality (physics) , metal , supramolecular chirality , polymer chemistry , nanotechnology , chemical engineering , crystallography , chemistry , organic chemistry , polymer , crystal structure , physics , nambu–jona lasinio model , chiral symmetry breaking , quantum mechanics , quark , metallurgy , composite material , engineering

Macroscopically chiral nanospheres and nanotubes composed of helical copolymers are described on page 238 by F. Freire, R. Riguera, and co‐workers. The presence of a donor co‐solvent either activates or deactivates cation–π supramolecular interactions on the chiral monomers of the copolymer, generating either P or M helical senses in the nanostructure through the ‘Sergeants and Soldiers’ effect.

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