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One‐Step In Situ Growth of Iron–Nickel Sulfide Nanosheets on FeNi Alloy Foils: High‐Performance and Self‐Supported Electrodes for Water Oxidation
Author(s) -
Yuan ChengZong,
Sun ZhongTi,
Jiang YiFan,
Yang ZhengKun,
Jiang Nan,
Zhao ZhiWei,
Qazi Umair Yaqub,
Zhang WenHua,
Xu AnWu
Publication year - 2017
Publication title -
small
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.785
H-Index - 236
eISSN - 1613-6829
pISSN - 1613-6810
DOI - 10.1002/smll.201604161
Subject(s) - overpotential , tafel equation , oxygen evolution , water splitting , materials science , nickel sulfide , chemical engineering , electrode , sulfide , nickel , alloy , catalysis , noble metal , inorganic chemistry , metal , metallurgy , electrochemistry , chemistry , biochemistry , photocatalysis , engineering
Efficient and durable oxygen evolution reaction (OER) catalysts are highly required for the cost‐effective generation of clean energy from water splitting. For the first time, an integrated OER electrode based on one‐step direct growth of metallic iron–nickel sulfide nanosheets on FeNi alloy foils (denoted as FeNi 3 S 2 /FeNi) is reported, and the origin of the enhanced OER activity is uncovered in combination with theoretical and experimental studies. The obtained FeNi 3 S 2 /FeNi electrode exhibits highly catalytic activity and long‐term stability toward OER in strong alkaline solution, with a low overpotential of 282 mV at 10 mA cm −2 and a small Tafel slope of 54 mV dec −1 . The excellent activity and satisfactory stability suggest that the as‐made electrode provides an attractive alternative to noble metal‐based catalysts. Combined with density functional theory calculations, exceptional OER performance of FeNi 3 S 2 /FeNi results from a combination of efficient electron transfer properties, more active sites, the suitable O 2 evolution kinetics and energetics benefited from Fe doping. This work not only simply constructs an excellent electrode for water oxidation, but also provides a deep understanding of the underlying nature of the enhanced OER performance, which may serve as a guide to develop highly effective and integrated OER electrodes for water splitting.