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In Situ Observation of Crystallization of Methylammonium Lead Iodide Perovskite from Microdroplets
Author(s) -
Li Yahui,
Zhao Zhenhao,
Lin Feng,
Cao Xiaobing,
Cui Xian,
Wei Jinquan
Publication year - 2017
Publication title -
small
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.785
H-Index - 236
eISSN - 1613-6829
pISSN - 1613-6810
DOI - 10.1002/smll.201604125
Subject(s) - crystallization , iodide , nucleation , perovskite (structure) , materials science , nanocrystalline material , chemical engineering , adduct , solubility , halide , crystallography , chemistry , inorganic chemistry , nanotechnology , organic chemistry , engineering
It is of great importance to investigate the crystallization of organometallic perovskite from solution for enhancing performance of perovskite solar cells. Here, this study develops a facile method for in situ observation of crystallization and growth of the methylammonium lead iodide (MAPbI 3 ) perovskite from microdroplets ejected by an alternating viscous and inertial force jetting method. It is found that there are two crystallization modes when MAPbI 3 grows from the CH 3 NH 3 I (MAI)/PbI 2 / N , N ‐dimethylformamide (DMF) solution: needle precursors and granular perovskites. Generally, needle Lewis adduct of MAPbI 3 ·DMF tends to nucleate and grow from the solution due to low solubility of PbI 2 . The growth of MAPbI 3 ·DMF depends on both the concentration of MAI and temperature. It tends to form large perovskite domains on substrates at high temperature. The MAPbI 3 ·DMF coverts to nanocrystalline perovskite due to lattice shrinkage when DMF molecules escape from the Lewis adduct. Granular perovskite can also directly nucleate from the solution at high concentration of MAI due to compositional segregation.