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Strengthened Synergistic Effect of Metallic M x P y (M = Co, Ni, and Cu) and Carbon Layer via Peapod‐Like Architecture for Both Hydrogen and Oxygen Evolution Reactions
Author(s) -
Bai Yuanjuan,
Fang Ling,
Xu Haitao,
Gu Xiao,
Zhang Huijuan,
Wang Yu
Publication year - 2017
Publication title -
small
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.785
H-Index - 236
eISSN - 1613-6829
pISSN - 1613-6810
DOI - 10.1002/smll.201603718
Subject(s) - bifunctional , catalysis , electrocatalyst , materials science , metal , carbon fibers , hydrogen , layer (electronics) , chemical engineering , nanotechnology , electrode , electrochemistry , chemistry , composite material , composite number , metallurgy , organic chemistry , engineering
The smooth electric transmission is crucial for the high‐efficient electrocatalysis. Herein, a series of peapod‐like metallic M x P y /C (M = Co, Ni, and Cu) composites is developed as bifunctional catalysts toward hydrogen and oxygen evolution reactions. For the first time, the metallic property of Cu 3 P is confirmed through the theoretical calculation. The in‐depth composition, structural and catalytic mechanism analysis of M x P y /C discloses that the comparable activity and considerable durability of these catalysts mainly result from the strengthened synergistic effect between metallic M x P y and carbon layer based on the unique peapod‐like architecture. Especially, the atomic contact between M x P y and carbon not only provides an open channel for electronic transmission but also ensures the integrity of peapod‐like structure. Furthermore, the high electric conductivity of the inner metallic M x P y and the outer carbon layer endows the M x P y /C catalyst with rapid charge migration during the electrocatalytic pathway. These findings shed light on the origin of high catalytic activity of M x P y /C and open a path for purposefully rationally synthesizing superior electrocatalysts.