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In Situ Synthesis of Metal Sulfide Nanoparticles Based on 2D Metal‐Organic Framework Nanosheets
Author(s) -
Lu Qipeng,
Zhao Meiting,
Chen Junze,
Chen Bo,
Tan Chaoliang,
Zhang Xiao,
Huang Ying,
Yang Jian,
Cao Feifei,
Yu Yifu,
Ping Jianfeng,
Zhang Zhicheng,
Wu XueJun,
Zhang Hua
Publication year - 2016
Publication title -
small
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.785
H-Index - 236
eISSN - 1613-6829
pISSN - 1613-6810
DOI - 10.1002/smll.201600976
Subject(s) - nanoparticle , sulfide , nanosheet , porphyrin , metal , metal organic framework , materials science , nanotechnology , photocurrent , in situ , computer science , chemistry , photochemistry , optoelectronics , organic chemistry , metallurgy , adsorption
A facile in situ synthetic method is developed to synthesize metal sulfide nanoparticles based on 2D M‐TCPP (M = Cu, Cd, or Co, TCPP = tetrakis(4‐carboxyphenyl)porphyrin)) metal‐organic framework nanosheets. The obtained CuS/Cu‐TCPP composite nanosheet is used as the active material in photoelectrochemical cells, showing notably increased photocurrent due to the improved exciton separation and charge carrier transport.