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Metal–Organic Frameworks: Encapsulation of Mono‐ or Bimetal Nanoparticles Inside Metal–Organic Frameworks via In situ Incorporation of Metal Precursors (Small 22/2015)
Author(s) -
Chen Liyu,
Chen Xiaodong,
Liu Hongli,
Li Yingwei
Publication year - 2015
Publication title -
small
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.785
H-Index - 236
eISSN - 1613-6829
pISSN - 1613-6810
DOI - 10.1002/smll.201570125
Subject(s) - bimetal , metal , metal organic framework , nanoparticle , materials science , encapsulation (networking) , in situ , nanotechnology , chemical engineering , chemistry , organic chemistry , metallurgy , computer network , adsorption , computer science , engineering
Y. Li and co‐workers describe a facile and efficient in‐situ incorporation method for the encapsulation of a metal precursor, achieving good control over the location and composition of metal nanoparticles within MOFs. On page 2642, it is shown that the employment of a mixed donor ligand could allow its assembly with the hard oxophilic metal cation (Zr 4+ ) to construct MOF and incorporation of the soft nitrophilic metal precursors (Pd 2+ and Ni 2+ ) in one step.