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Ternary Sn–Ti–O Based Nanostructures as Anodes for Lithium Ion Batteries
Author(s) -
Wang Hongkang,
Huang He,
Niu Chunming,
Rogach Andrey L.
Publication year - 2015
Publication title -
small
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.785
H-Index - 236
eISSN - 1613-6829
pISSN - 1613-6810
DOI - 10.1002/smll.201402682
Subject(s) - materials science , ternary operation , anode , lithium (medication) , nanostructure , ion , nanotechnology , chemical engineering , electrode , chemistry , computer science , organic chemistry , medicine , engineering , programming language , endocrinology
SnO x ( x = 0, 1, 2) and TiO 2 are widely considered to be potential anode candidates for next generation lithium ion batteries. In terms of the lithium storage mechanisms, TiO 2 anodes operate on the base of the Li ion intercalation–deintercalation, and they typically display long cycling life and high rate capability, arising from the negligible cell volume change during the discharge–charge process, while their performance is limited by low specific capacity and low electronic conductivity. SnO x anodes rely on the alloying–dealloying reaction with Li ions, and typically exhibit large specific capacity but poor cycling performance, originating from the extremely large volume change and thus the resultant pulverization problems. Making use of their advantages and minimizing the disadvantages, numerous strategies have been developed in the recent years to design composite nanostructured Sn–Ti–O ternary systems. This Review aims to provide rational understanding on their design and the improvement of electrochemical properties of such systems, including SnO x –TiO 2 nanocomposites mixing at nanoscale and nanostructured Sn x Ti 1‐ x O 2 solid solutions doped at the atomic level, as well as their combinations with carbon‐based nanomaterials.