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Dendrite‐Free Nanostructured Anode: Entrapment of Lithium in a 3D Fibrous Matrix for Ultra‐Stable Lithium–Sulfur Batteries
Author(s) -
Cheng XinBing,
Peng HongJie,
Huang JiaQi,
Wei Fei,
Zhang Qiang
Publication year - 2014
Publication title -
small
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.785
H-Index - 236
eISSN - 1613-6829
pISSN - 1613-6810
DOI - 10.1002/smll.201401837
Subject(s) - anode , faraday efficiency , materials science , electrolyte , lithium (medication) , dendrite (mathematics) , electrode , sulfur , chemical engineering , electrochemistry , cathode , chemistry , metallurgy , medicine , geometry , mathematics , engineering , endocrinology
Entrapment of free lithium in a 3D fibrous Li 7 B 6 framework allows LiB nanostructured anodes with stable interfaces between the electrolyte and the electrode, which retards the formation of lithium dendrites. A lithium–sulfur cell with a nanostructured anode is created with a high Coulombic efficiency and high capacity retention rate of 36.3% after 2000 cycles.

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