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Mixed Valence Materials: Prussian Blue Analogues of Reduced Dimensionality (Small 16/2012)
Author(s) -
Gengler Régis Y. N.,
Toma Luminita M.,
Pardo Emilio,
Lloret Francesc,
Ke Xiaoxing,
Van Tendeloo Gustaaf,
Gournis Dimitrios,
Rudolf Petra
Publication year - 2012
Publication title -
small
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.785
H-Index - 236
eISSN - 1613-6829
pISSN - 1613-6810
DOI - 10.1002/smll.201290088
Subject(s) - prussian blue , aluminosilicate , materials science , superparamagnetism , monolayer , valence (chemistry) , curse of dimensionality , nanotechnology , chemical engineering , chemistry , magnetization , organic chemistry , physics , computer science , catalysis , electrode , machine learning , electrochemistry , quantum mechanics , magnetic field , engineering
The cover image shows an artistic view of the “on surface” synthesis of low‐dimensional Prussian Blue Analogues (PBAs) on a layered aluminosilicate clay mineral. The network of spheres illustrates the innovative bi‐dimensional arrangement of PBAs as synthesized in a self‐limited cation exchange reaction on the clay surface. Well‐packed clay platelet monolayers (visible in the blue background), deposited by a Langmuir–Schaefer approach, are used here as templates. This low‐dimensional assembly preserves a high T c of ∼80 K and gives rise to a new magnetic behavior between superparamagnetic and spin‐glass properties. For more information, please refer to the Full Paper “Prussian Blue Analogues of Reduced Dimensionality” by F. Lloret, D. Gournis, P. Rudolf and co‐workers, beginning on page 2532 .