Premium
Direct Laser‐Patterned Micro‐Supercapacitors from Paintable MoS 2 Films
Author(s) -
Cao Liujun,
Yang Shubin,
Gao Wei,
Liu Zheng,
Gong Yongji,
Ma Lulu,
Shi Gang,
Lei Sidong,
Zhang Yunhuai,
Zhang Shengtao,
Vajtai Robert,
Ajayan Pulickel M.
Publication year - 2013
Publication title -
small
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.785
H-Index - 236
eISSN - 1613-6829
pISSN - 1613-6810
DOI - 10.1002/smll.201203164
Subject(s) - supercapacitor , materials science , capacitance , electrode , fabrication , nanotechnology , capacitor , optoelectronics , micrometer , energy storage , graphene , electrochemistry , electrical engineering , optics , voltage , medicine , power (physics) , chemistry , alternative medicine , physics , pathology , quantum mechanics , engineering
Micrometer‐sized electrochemical capacitors have recently attracted attention due to their possible applications in micro‐electronic devices. Here, a new approach to large‐scale fabrication of high‐capacitance, two‐dimensional MoS 2 film‐based micro‐supercapacitors is demonstrated via simple and low‐cost spray painting of MoS 2 nanosheets on Si/SiO 2 chip and subsequent laser patterning. The obtained micro‐supercapacitors are well defined by ten interdigitated electrodes (five electrodes per polarity) with 4.5 mm length, 820 μm wide for each electrode, 200 μm spacing between two electrodes and the thickness of electrode is ∼0.45 μm. The optimum MoS 2 ‐based micro‐supercapacitor exhibits excellent electrochemical performance for energy storage with aqueous electrolytes, with a high area capacitance of 8 mF cm −2 (volumetric capacitance of 178 F cm −3 ) and excellent cyclic performance, superior to reported graphene‐based micro‐supercapacitors. This strategy could provide a good opportunity to develop various micro‐/nanosized energy storage devices to satisfy the requirements of portable, flexible, and transparent micro‐electronic devices.