Photoinduced Methylation of Graphene | Zendy

Liao Lei | Zendy; Song Zehao | Zendy; Zhou Yu | Zendy; Wang Huan | Zendy; Xie Qin | Zendy; Peng Hailin | Zendy; Liu Zhongfan | Zendy

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Photoinduced Methylation of Graphene

Author(s) -

Liao Lei,

Song Zehao,

Zhou Yu,

Wang Huan,

Xie Qin,

Peng Hailin,

Liu Zhongfan

Publication year - 2013

Publication title -

small

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 3.785

H-Index - 236

eISSN - 1613-6829

pISSN - 1613-6810

DOI - 10.1002/smll.201203069

Subject(s) - graphene , basal plane , methylation , reactivity (psychology) , enhanced data rates for gsm evolution , covalent bond , grafting , materials science , nanotechnology , computer science , chemistry , organic chemistry , medicine , biochemistry , telecommunications , crystallography , alternative medicine , pathology , gene , polymer

Covalent grafting of methyl groups onto the basal plane of graphene is achieved through a photochemical reaction between graphene and di‐ tert ‐butyl peroxide. The methylation of graphene is found to be reversible. The edge of single‐layer graphene shows the largest methylation reactivity, which provides a route to tailor the edge state of graphene.

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