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Plasmonic Nanogap‐Enhanced Raman Scattering Using a Resonant Nanodome Array
Author(s) -
Wu HsinYu,
Choi Charles J.,
Cunningham Brian T.
Publication year - 2012
Publication title -
small
Language(s) - English
Resource type - Book series
SCImago Journal Rank - 3.785
H-Index - 236
eISSN - 1613-6829
pISSN - 1613-6810
ISBN - 978-1-4673-1839-6
DOI - 10.1002/smll.201200712
Subject(s) - materials science , raman scattering , surface plasmon resonance , plasmon , scattering , resonance (particle physics) , optoelectronics , raman spectroscopy , substrate (aquarium) , light scattering , localized surface plasmon , excited state , surface plasmon , optics , nanotechnology , nanoparticle , physics , oceanography , particle physics , geology , nuclear physics
The optical properties and surface‐enhanced Raman scattering (SERS) of plasmonic nanodome array (PNA) substrates in air and aqueous solution are investigated. PNA substrates are inexpensively and uniformly fabricated with a hot spot density of 6.25 × 10 6 mm −2 using a large‐area nanoreplica moulding technique on a flexible plastic substrate. Both experimental measurement and numerical simulation results show that PNAs exhibit a radiative localized surface plasmon resonance (LSPR) due to dipolar coupling between neighboring nanodomes and a non‐radiative surface plasmon resonance (SPR) resulting from the periodic array structure. The high spatial localization of electromagnetic field within the ∼10 nm nanogap together with the spectral alignment between the LSPR and excited and scattered light results in a reliable and reproducible spatially averaged SERS enhancement factor (EF) of 8.51 × 10 7 for Au‐coated PNAs. The SERS enhancement is sufficient for a wide variety of biological and chemical sensing applications, including detection of common metabolites at physiologically relevant concentrations.