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Investigating the Mechanism of Hysteresis Effect in Graphene Electrical Field Device Fabricated on SiO 2 Substrates using Raman Spectroscopy
Author(s) -
Xu Hua,
Chen Yabin,
Zhang Jin,
Zhang Haoli
Publication year - 2012
Publication title -
small
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.785
H-Index - 236
eISSN - 1613-6829
pISSN - 1613-6810
DOI - 10.1002/smll.201102468
Subject(s) - graphene , raman spectroscopy , materials science , hysteresis , graphene nanoribbons , doping , substrate (aquarium) , field effect transistor , nanotechnology , chemical physics , chemical engineering , optoelectronics , condensed matter physics , transistor , chemistry , optics , voltage , oceanography , physics , engineering , quantum mechanics , geology
The hysteresis effect is a common problem in graphene field‐effect transistors (FETs). Usually, the external doping to graphene is considered to be responsible for the hysteresis behavior, but is not yet clearly understood. By monitoring the doping of graphene and the hysteresis in graphene FETs under different atmospheres using in situ Raman spectroscopy, it is confirmed that the electrochemical doping of O 2 /H 2 O redox couple to graphene is responsible for the hysteresis effect. In addition, Raman spectra of graphene on SiO 2 substrate show stronger doping than that suspended, which indicates that SiO 2 substrate plays an important role in the doping of graphene. Herein it is proposed that the doping species (H 2 O and O 2 ) are bounded at the interface of graphene/SiO 2 substrate by hydrogen‐bonds with the silanol groups on SiO 2 substrate. The dynamic equilibrium process of the charge‐transfer between H 2 O/O 2 redox couple and graphene under electrical field modulation is carefully analyzed using Marcus–Gerischer theory. This work provides a clear view to the mechanism of the hysteresis effect, and is of benefit to a reliable design to suppress the hysteresis in graphene FETs.