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Facile Synthesis of Vanadium Metal–Organic Frameworks and their Magnetic Properties
Author(s) -
Centrone Andrea,
Harada Takuya,
Speakman Scott,
Hatton T. Alan
Publication year - 2010
Publication title -
small
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.785
H-Index - 236
eISSN - 1613-6829
pISSN - 1613-6810
DOI - 10.1002/smll.201000773
Subject(s) - vanadium , metal organic framework , materials science , organic molecules , nanotechnology , metal , organic synthesis , molecule , microwave , computer science , organic chemistry , chemistry , metallurgy , catalysis , telecommunications , adsorption
The facile microwave syntheses of MIL‐47 and six new vanadium‐metal–organic‐framework (V‐MOF) materials are described. Small changes in the material crystal structure or removal of guest molecules affects the interactions between the V ions and, consequently, the magnetic properties of the MOF (see image).