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Density Fluctuations and Phase Transitions of Ferroelectric Polymer Nanowires
Author(s) -
Serghei Anatoli,
Lutkenhaus Jodie L.,
Miranda Daniel F.,
McEnnis Kathleen,
Kremer Friedrich,
Russell Thomas P.
Publication year - 2010
Publication title -
small
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.785
H-Index - 236
eISSN - 1613-6829
pISSN - 1613-6810
DOI - 10.1002/smll.201000562
Subject(s) - materials science , ferroelectricity , phase transition , nanoscopic scale , nanowire , dielectric , condensed matter physics , ferroelectric polymers , permittivity , polymer , phase (matter) , length scale , chemical physics , nanotechnology , optoelectronics , composite material , chemistry , physics , organic chemistry , quantum mechanics
Phase transitions of polymeric materials are accompanied by changes in density as a function of temperature. Being able to measure these changes in polymeric systems in one, two or three dimensions on the nanoscopic length‐scale is a challenge, but it would provide a simple route to assess phase transitions in nanoscopically confined systems. It is shown that the measurement of the dielectric permittivity in the high frequency limit (in spectral regions not affected by dielectric dispersions) offers an effective and very sensitive means to assess density fluctuations, and hence phase transitions, in nanoscopic systems. The sensitivity of this approach is demonstrated by assessing the phase transition behavior of ferroelectric polymer nanowires confined within alumina membranes. No significant shifts in the Curie transition are observed down to pore diameters as small as 15 nm.